A piezoelectric deep material network (PDMN) is proposed to efficiently homogenize two-phase piezoelectric composites. The framework embeds electromechanical homogenization relations into its architecture, enabling physics-informed, semi-analytical predictions with over three orders of magnitude lower computational cost than direct numerical simulation, validated on PVDF-LiNbO3 and viscoelastic-piezoelectric composites under nonlinear loading.